A new route for substitution of the bridging acetate on the oxo-centered triruthenium acetate cluster.
نویسندگان
چکیده
Deacetoxylation of the oxo-centered triruthenium acetate cluster by acetyl chloride or triethylsilyl chloride led to the formation of a versatile precursor [Ru(3)O(OAc)(5)(Cl)(4-methylpyridine)(2)(CNt-Bu)], whose chloro ligand was readily substituted by other bridging ligands, i.e. alkoxides, carboxylates or sulfides.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 13 شماره
صفحات -
تاریخ انتشار 2009